主题：氘代试剂的化学位移

NMR溶剂的化学位移为了方便讨论,贴出NMR溶剂的化学位移

NMR Solvents  Solvent  Formula  1H shifts  13C shifts  <--mp °C    bp °C    --> mp °C    bp °C 
Acetic Acid-d4 CD3COOD 2.0, 11.7 20.0, 180.0 16.6 117.9
Acetone-d6 CD3COCD3 2.09 29.9, 206.7 -94.7 56.1
Acetonitrile-d3 CD3CN  1.94 1.4, 118.7 -43.8 81.6
Benzene-d6 C6D6  7.16 128.4 5.5 80.1
Carbon Disulphide CS2 none  192.8 -11.6 46.3
Carbon Tetrachloride CCl4 none 96.7 -23.0 76.8
Chloroform-d CDCl3  7.24  77.23 -63.5 61.3
Dichloromethane-d2 CD2Cl2  5.32 54.0 -95.1 40.8
Diethyl Ether (-100 °C)  (CH3CH2)2O  ?, 66.51  -116.3 34.6
Dimethyl Ether (-100 °C)    CH3OCH3  3.2  60.08  -138.5 -23
N,N-Dimethyl formamide-d7      Me2NCHO  2.95, 2.75, 8.03 29.8, 34.9, 163.2  -61.? 153.?
Dimethyl Sulfoxide-d6  CD3SOCD3  2.50  39.5 18.6 189.0

1,4-Dioxan  (OCH2CH2)2    3.53  66.7 11.8 101.4
Ethanol-d6  CD3CD2OD  1.11, 3.56, 5.19    17.3, 57.0 -117 78.3
Methanol-d4  CD3OD  3.31, 4.78  49.2  -97.8 64.6
Nitrobenzene  C6D5NO2  7.5, 7.7, 8.1  123, 129, 135  5.7 210.8
Nitromethane-d3  CD3NO2  4.3  57.3  -28.6 101.2
Pyridine-d5  C5D5N  7.22, 7.58, 8.74  123.9, 135.9, 150.2      -41.6 115.3
1,1,2,2-Tetrachloroethane    CHCl2CHCl2  ?  75.5  -43.8 146.3
Tetrahydrofuran-d8  C4D8O  1.73, 3.58  25.4, 67.6  -108.5 65.4
Tetrahydrofuran -100 °C  C4H8O  ?, 67.96   
Toluene-d8  C6D5CD3  2.09, 6.98, 7.00, 7.09      20.4, 125.5, 128.3, 129.4, 137.9    -94.9 110.6
Trichlorofluoromethane  CFCl3  none  117.6  -111 23.7
Trifluoroacetic Acid-d4  CF3COOD  11.5  116.6, 164.2  -15.3 72.4
Trifluoroethanol-d3  CF3CD2OD  3.88, 5.02  61.5, 126.3  -15.3 72.4
Water  D2O  4.8  none  0.0 100.0
Solvent  Formula  1H shifts  13C shifts  <--mp °C    bp °C    --> mp °C    bp °C