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题目:A comparative study of the structural organization of nickel(II) and copper(II) complexes with dialkyl-substituted and cyclic diethyldithiocarbamate ligands by x-ray crystallography, EPR, and CP/MAS 13C and 15N NMR.
作者:Ivanov, A. V.; Ivakhnenko, E. V.; Forsling, Willis; Gerasimenko, A. V.; Bukvetskii, B. V.
期刊:Zhurnal Neorganicheskoi Khimii  (2002),  47(3),  468-480
摘要:


The crystal and mol. structures were studied of M(S2CNR2)2 complexes where M = Cu(II) or Ni(II), R = Me, Et, Pr, iso-Pr, (CH2)5, (CH2)6, and (CH2)4O.  The complexes are all square planar and coordinated with all 4 S atoms.  Distorted geometry is obsd. for the bis(morpholinedithiocarbamato)Cu(II).  Substitutional effects are discussed based on the NMR data.  The Ni(S2CN(C3H7)2)2 has 2 types of nonequiv. mols. in the unit cell.  Ni(S2CN(CH2)6)2 has 2 nonequiv. intermol. dithiocarbamato groups.
链接:http://pure.ltu.se/portal/en/publications/a-comparative-study-of-the-structural-organization-of-nickelii-and-copperii-complexes-with-dialkylsubstituted-and-cyclic-dithiocarbamate-ligands-by-xray-singlecrystal-diffraction-epr-and-cpmas-c13-and-n15-nmr(5065d950-dcf2-11db-9cae-000ea68e967b).html
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