我学校可下载sciencedirect,可为何找不到你这个杂志呢?请楼主确认一下。 是否指的Journal of Electroanalytical Chemistry ? 可 101卷有19-36,没有19-28啊?是这篇文献吗? Theory of differential pulse polarography at expanding or stationary planar electrodes for quasi-reversible or totally irreversible reactions 作者:Koichi Aoki and Janet Osteryoung 如是,请楼主明示。
Journal of Electroanalytical Chemistry Volume 101, Issue 1 , 25 July 1979, Pages 19-28 文章题目:General expression of the linear potential sweep voltammogram in the case of diffusionless electrochemical systems 摘要:Abstract The equation of the linear potential sweep voltammogram is derived for any degree of reversibility of the electrochemical reaction for the following methods: surface voltammetry when both the oxidized and the reduced forms are strongly adsorbed, and a Langmuir isotherm is obeyed, thin layer voltammetry, and linear potential sweep coulometry. The results are expressed in one mathematical form valid for the three cases. The transfer coefficient and the rate constant of the electrochemical reaction can be deduced from an experimental study of the variations of the peak potentials as a function of the sweep rate. 作者:E. Lavirona
aLaboratoire de Polarographie Organique associé au C.N.R.S., Faculté des Sciences Gabriel, 21100 Dijon France