Abstract The anionic products from the reactions between metal(M=Ag，Au，Pd，Pt，Pb and Bi)vapour produced by laser ablation and hexafluorobenzene seeded in carrier gas(Ar1 were studied by means of a homemade reflectron time-of-flight mass spectrometry(RTOF-MS)．Experimental results show that the dominant products were【M C6F6]一 complexes for the reactions of Ag，Au，Pd and Pt with C6F6，while the dominant products were【M C6F5]一complexes f0r the reactions of Pb an d Bi with C6F6．The formation mechanisms of the products，including the adsorption of metal cluster anions on hexafluorobenzene and the C— F cleavage induced by metal cluster anions．were discussed．
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