主题：【求助】联苯钠的性状

查询到联苯钠的英文版MSDS，希望对楼主有所帮助

Solution Name: SODIUM BIPHENYL REAGENT
Cas: 5137-46-2
Formula: C6H5C6H5NA
Formula Wt: 177.20
Product Use: N/A
Chemical Family: RESEARCH AND DEVELOPMENT USE ONLY
Catalog Num: N/A
Effective Date: EFFECTIVE:05/01/89ISSUED: 04/14/90REVIEWED: 1/1/97
Components: COMPONENTCAS NO.WEIGHT %OSHA/PELACGIH/TLV
SODIUM BIPHENYL5137-46-214N/EN/E
1,2-DIMETHOXYETHANE110-71-472N/EN/E
TOLUENE108-88-314100PPM100PPM
Health: 2MODERATE
Flammability: 4EXTREME (FLAMMABLE)
Reactivity: 2MODERATE
Contact: 2MODERATE
Physical Info: BOILING POINT: 85 C (185 F)VAPOR PRESSURE (MMHG):
24
(AT 760 MM HG) (20 C)
MELTING POINT: N/AVAPOR DENSITY (AIR=1): N/A
SPECIFIC GRAVITY: 0.87EVAPORATION RATE: N/A
(H2O=1)
SOLUBILITY(H20): APPRECIABLE (>10%)% VOLATILES BY
VOLUME: 86
(21 C)
PH: N/A
ODOR THRESHOLD (P.P.M.): N/A PHYSICAL STATE: LIQUID
COEFFICIENT WATER/OIL DISTRIBUTION: N/A
APPEARANCE & ODOR: DARK GREEN LIQUID. FAINT
ETHER-LIKE ODOR.
Fire Hazard Info:
FLASH POINT (CLOSED CUP): -9 C (15 F)
AUTOIGNITION TEMPERATURE: N/A
FLAMMABLE LIMITS:UPPER - N/ALOWER - N/A
FIRE EXTINQUISHING MEDIA
USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL
OR ORDINARY FOAM.
SPECIAL FIRE-FIGHTING PROCEDURES
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE
EQUIPMENT AND SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACEPIECE
OPERATED IN POSITIVE PRESSURE
MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN
BE DONE WITHOUT RISK.USE
WATER TO KEEP FIRE -EXPOSED CONTAINERS COOL.
UNUSUAL FIRE & EXPLOSION HAZARDS
VAPORS MAY FLOW ALONG SURFACES TO DISTANT
IGNITION SOURCES AND FLASH BACK.
CLOSED CONTAINERS EXPOSED TO HEAT MAY
EXPLODE.CONTACT WITH STRONG
OXIDIZERS MAY CAUSE FIRE.
TOXIC GASES PRODUCED
NONE IDENTIFIED
EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT
NONE IDENTIFIED.
EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE
NONE IDENTIFIED.
Health Hazard
Info:
THRESHOLD LIMIT VALUE (TLV/TWA):NOT ESTABLISHED
SHORT-TERM EXPOSURE LIMIT (STEL): NOT
ESTABLISHED
PERMISSIBLE EXPOSURE LIMIT (PEL): NOT ESTABLISHED
TOXICITY OF COMPONENTS
ORAL RAT LD50 FOR TOLUENE5000 MG/KG
INTRAPERITONEAL MOUSE LD50 FOR TOLUENE1.12
MG/KG
SKIN RABBIT LD50 FOR TOLUENE14G/KG
INHALATION-8HR MOUSE LC50 FOR TOLUENE5320 PPM
CARCINOGENICITY:NTP: NOIARC: NOZ LIST: NOOSHA
REG: NO
CARCINOGENICITY
NONE IDENTIFIED.
REPRODUCTIVE EFFECTS
NONE IDENTIFIED.
EFFECTS OF OVEREXPOSURE
INHALATION: SEVERE IRRITATION OF RESPIRATORY
SYSTEM, MAY CAUSE
NARCOSIS
SKIN CONTACT:IRRITATION
EYE CONTACT:IRRITATION
SKIN ABSORPTION: MAY BE HARMFUL
INGESTION:NONE IDENTIFIED
CHRONIC EFFECTS: NONE IDENTIFIED
TARGET ORGANS
NONE IDENTIFIED
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY
EXPOSURE
NONE IDENTIFIED
PRIMARY ROUTES OF ENTRY
NONE INDICATED
EMERGENCY AND FIRST AID PROCEDURES
INGESTION:IF SWALLOWED AND THE PERSON IS
CONSCIOUS, IMMEDIATELY GIVE
LARGE AMOUNTS OF WATER.GET MEDICAL ATTENTION.
INHALATION:IF INHALED, REMOVE TO FRESH AIR.IF NOT
BREATHING, GIVE
ARTIFICIAL RESPIRATION.IF BREATHING IS DIFFICULT,
GIVE
OXYGEN.
SKIN CONTACT: IN CASE OF CONTACT, FLUSH SKIN WITH
WATER.
EYE CONTACT:IN CASE OF EYE CONTACT, IMMEDIATELY
FLUSH WITH PLENTY OF
WATER FOR AT LEAST 15 MINUTES.
NOTE: CHEMICAL SUBSTANCES THAT ARE
MANUFACTURED OR IMPORTED IN SMALL
QUANTITIES SOLELY FOR THE USE IN RESEARCH &
DEVELOPMENT ARE NOT SUBJECT TO
THE NOTIFICATION REQUIREMENTS OF THE TOXIC
SUBSTANCES CONTROL ACT (TSCA),
15 USC 2604 (H) ET SEQ. REFERENCE - 40 CFR 720.36
SARA/TITLE III HAZARD CATEGORIES AND LISTS
ACUTE: YES CHRONIC: YES FLAMMABILITY: YES
PRESSURE: NOREACTIVITY: NO
EXTREMELY HAZARDOUS SUBSTANCE: NO
CERCLA HAZARDOUS SUBSTANCE:YESCONTAINS
BENZENE, METHYL- (RQ = 1000 LBS)
SARA 313 TOXIC CHEMICALS: YESCONTAINS TOLUENE
GENERIC CLASS: C01
TSCA INVENTORY: NO
Reactivity Info:
STABILITY: STABLEHAZARDOUS POLYMERIZATION: WILL
NOT OCCUR
CONDITIONS TO AVOID:AIR, MOISTURE, HEAT, FLAME,
OTHER SOURCES OF IGNITION
INCOMPATIBLES:STRONG OXIDIZING AGENTS
DECOMPOSITION PRODUCTS: CARBON MONOXIDE,
CARBON DIOXIDE
Spill Disposal
Info:
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR
DISCHARGE
WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE CLOTHING. SHUT
OFF IGNITION SOURCES; NO FLARES, SMOKING OR
FLAMES IN AREA.STOP LEAK IF
YOU CAN DO SO WITHOUT RISK.USE WATER SPRAY TO
REDUCE VAPORS.TAKE UP
WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT
MATERIAL AND PLACE INTO
CONTAINER FOR LATER DISPOSAL.FLUSH AREA WITH
WATER.
J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS
RECOMMENDED FOR SPILLS OF THIS
PRODUCT.
DISPOSAL PROCEDURE
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, AND LOCAL
ENVIRONMENTAL REGULATIONS.
EPA HAZARDOUS WASTE NUMBER:D001 (IGNITABLE
WASTE)
Protection Info:
VENTILATION:USE ADEQUATE GENERAL OR LOCAL
EXHAUST VENTILATION TO
KEEP VAPOR AND MIST LEVELS AS LOW AS POSSIBLE.
RESPIRATORY PROTECTION: NONE REQUIRED WHERE
ADEQUATE VENTILATION CONDITIONS
EXIST.IF AIRBORNE CONCENTRATION IS HIGH, A
CHEMICAL
CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR
CARTRIDGE IS
RECOMMENDED.IF CONCENTRATION EXCEEDS
CAPACITY OF
CARTRIDGE RESPIRATOR, A SELF-CONTAINED
BREATHING
APPARATUS IS ADVISED.
EYE/SKIN PROTECTION:SAFETY GOGGLES, UNIFORM,
APRON, PROPER GLOVES ARE
RECOMMENDED.
Storage Handling
Info:
SAF-T-DATA* STORAGE COLOR CODE: RED (FLAMMABLE)
STORAGE REQUIREMENTS
KEEP CONTAINER TIGHTLY CLOSED.STORE IN A COOL,
DRY, WELL-VENTILATED,
FLAMMABLE LIQUID STORAGE AREA OR CABINET.
PRODUCT MUST BE REFRIGERATED AT
2 - 8 C (36 - 46 F).
SPECIAL PRECAUTIONS
BOND AND GROUND CONTAINERS WHEN
TRANSFERRING LIQUID.
Transportation
Info:
DOMESTIC (D.O.T.)
PROPER SHIPPING NAME:FLAMMABLE LIQUID, N.O.S.
(SODIUM BIPHENYL REAGENT)
HAZARD CLASS:FLAMMABLE LIQUID
UN/NA: UN1993
LABELS: FLAMMABLE LIQUID
REGULATORY REFERENCES: 49CFR 172.101; 173.119
INTERNATIONAL (I.M.O.)
PROPER SHIPPING NAME:FLAMMABLE LIQUIDS, N.O.S.
(SODIUM BIPHENYL REAGENT)
HAZARD CLASS:3.2 I.M.O. PAGE: 3084
UN: UN1993MARINE POLLUTANTS: NOPACKAGING
GROUP: II
LABELS: FLAMMABLE LIQUID
REGULATORY REFERENCES: 49CFR 172.102; PART 176;
IMO
AIR (I.C.A.O.)
PROPER SHIPPING NAME:FLAMMABLE LIQUIDS, N.O.S.
(SODIUM BIPHENYL REAGENT)
HAZARD CLASS:3.2
UN: UN1993PACKAGING GROUP: II
LABELS: FLAMMABLE LIQUID
REGULATORY REFERENCES: 49CFR 172.101; 173.6; PART
175; ICAO/IATA
U.S. CUSTOMS HARMONIZATION NUMBER: 38220000000
N/A = NOT APPLICABLE OR NOT AVAILABLE
N/E = NOT ESTABLISHED

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