主题:【求助】加急!六方晶系的问题

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hhhmonkey
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请问各位大侠,六方晶系中三指标的晶面指数和晶向指数是怎么转换的??有没有什么书给我推荐一下。
比如说六方晶系中(100)晶面所对应的晶向是[210],那么(102)晶面对应的晶向是多少啊??谢谢各位了,小弟急着用!!
推荐答案:蓝莓口香糖回复于2008/11/04

不必知道a和c的具体值,只要知道它们的比例就可以了。这个比例决定晶胞的形状。居然有XRD的数据,没有卡片也没关系,可以对数据做拟合,得到所有的晶体学参数。
补充答案:

迷失的精灵回复于2008/11/03

可参考以下网址:
http://www.ezkaoyan.com/school/fzu/Column7/2006-6-20/20066202722515.htm

654420787回复于2008/11/04

看这个对你有用不!
晶体学基础

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迷失的精灵
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可参考以下网址:
http://www.ezkaoyan.com/school/fzu/Column7/2006-6-20/20066202722515.htm
蓝莓口香糖
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以下转自http://en.wikipedia.org/wiki/Miller_index

With hexagonal and rhombohedral crystal systems, it is possible to use the Bravais-Miller index which has 4 numbers (h k i l)
i = −h − k.
Here h, k and l are identical to the Miller index, and i is a redundant index.
This four-index scheme for labeling planes in a hexagonal lattice makes permutation symmetries apparent. For example, the similarity between and is more obvious when the redundant index is shown.



In the figure at above, the (001) plane has a 3-fold symmetry: it remains unchanged by a rotation of 1/3 (2π/3 rad, 120°). The [100], [010] and the  directions are really similar. If S is the intercept of the plane with the axis, then
i = 1/S.
There are also ad hoc schemes (e.g. in the transmission electron microscopy literature) for indexing hexagonal lattice vectors (rather than reciprocal lattice vectors or planes) with four indices. However they don't operate by similarly adding a redundant index to the regular three-index set.

For example, the reciprocal lattice vector (hkl) as suggested above can be written as ha*+kb*+lc* if the reciprocal-lattice basis-vectors are a*, b*, and c*. For hexagonal crystals this may be expressed in terms of direct-lattice basis-vectors a, b and c as

Hence zone indices of the direction perpendicular to plane (hkl) are, in suitably-normalized triplet form, simply [2h+k,h+2k,l(3/2)(a/c)^2]. When four indices are used for the zone normal to plane (hkl), however, the literature often uses [h,k,-h-k,l(3/2)(a/c)^2] instead. Thus as you can see, four-index zone indices in square or angle brackets sometimes mix a single direct-lattice index on the right with reciprocal-lattice indices (normally in round or curly brackets) on the left.
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Last edit by drizzlemiao
654420787
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hhhmonkey
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也就是说我必须知道a和c的值才能通过那个公式推算出晶向吗??关键是我的物象在XRD中没有确定的PDF卡对应,我无法得知确定的a/c的值啊
蓝莓口香糖
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原文由 hhhmonkey 发表:
也就是说我必须知道a和c的值才能通过那个公式推算出晶向吗??关键是我的物象在XRD中没有确定的PDF卡对应,我无法得知确定的a/c的值啊

不必知道a和c的具体值,只要知道它们的比例就可以了。这个比例决定晶胞的形状。居然有XRD的数据,没有卡片也没关系,可以对数据做拟合,得到所有的晶体学参数。
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