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标题:Distinguishing Crude Oils from Heavy Fuel Oils by Polycyclic Aromatic Hydrocarbon Fingerprints.
作者:Liu, Xing1
Wang, Zhen1
Ma, Xindong1
Xu, Hengzhen1
Yao, Ziwei1 zwyao@nmemc.gov.cn
来源:Environmental Forensics. Jan2013, Vol. 14 Issue 1, p20-24. 5p. 3 Charts, 2 Graphs.
文献类型:Article
主题语:*PETROLEUM as fuel
*POLYCYCLIC aromatic hydrocarbons
*PRINCIPAL components analysis
地理术语:ANGOLA
MAURITANIA
TURKMENISTAN
作者提供的关键字:crude oils
diagnostic ratios
heavy fuel oils
principal component analysis (PCA)
NAICS/行业代码:412110 Petroleum and petroleum products merchant wholesalers
424720 Petroleum and Petroleum Products Merchant Wholesalers (except Bulk Stations and Terminals)
324110 Petroleum Refineries
454311 Heating oil dealers
摘要:A novel method for distinguishing heavy fuel oils from crude oils is proposed in this study. This method comprises gas chromatography-mass spectrometry analysis and principal component analysis (PCA) of the diagnostic ratios of selected polycyclic aromatic hydrocarbons (PAHs). The method was applied to 15 heavy fuel oils (B1 to B15) and 32 crude oils (C1 to C32) for distinction. Oil samples were collected from Turkmenistan,Korea, China,Vietnam,Morocco, Algeria, Sultan, Yemen, Saudi Arabia, Argentina,Russia, Indonesia, Brazil, Equatorial Guinea, Angola, and Mauritania. The discriminative power of PCA was enhanced through the selection oftypicalPAH diagnostic ratios, which could be used to distinguish petrogenic from pyrogenic PAHs. The two principal components (PC1 and PC2) account for over 75% of the variance. The method was confirmed to be highly efficient for distinguishing heavy fuel oils from crude oils, with a rapid and objective procedure under comprehensive considerations. [ABSTRACT FROM AUTHOR]
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作者单位:1National Marine Environmental Monitoring Center, and Inspection & Authentication Standard Lab of China Marine Surveillance, Dalian, China
ISSN:1527-5922
DOI:10.1080/15275922.2012.760178
入藏编号:85751034
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