原文由 tsu 发表:
看了那么多的不确定度计算实例,提个问题:在标准曲线拟合时,为什么不考虑每个点的不确定度—既然我们已经给出了每个点的不确定度。
本人已有一个整体解决方案,欢迎和我讨论。
关于标准曲线的不确定度,一般不考虑标准溶液的不确定度。这是基于最小二乘法的原理。
The LS assumes that the uncertainties of the values of the abscissa are cosiderably smaller than the uncertainty on the values of the ordinate therefore the usual uncertainty calculation procedures for c0 only reflect the uncertainty in the absorbance and not the uncertainty of the calibration standards, nor the inevitable correlations induced by successive dilution from the same stock. In this case, however, the uncertainty of the calibration standards issufficiently small to be neglected.
--------From EURACHEM / CITAC Guide CG 4