主题:为什么ICP-MS的样品溶液的介质最好是硝酸?

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yaohuaqing2006
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这是因为硝酸所带入的同位素H、N、O都是原来空气中就有的,并不带入新的同位素干扰。而硫酸和盐酸等会带入S、Cl等同位素的干扰,所以说用硝酸好一些。当然,S、Cl不会对测量元素产生干扰,那用硫酸、盐酸也没有问题。
qhzhangqy
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干扰少啊
如果用盐酸就会有大量氯根、氯氧的干扰啊
zhckj
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呵呵原来如此,原以为配样时加硝酸是防止其他元素不稳定的,呵呵
supercat
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For sample digestion, and dilution, HNO3 is the preferred choice, as it
produces the least new interferences in the plasma, but it is not always
ideal, since some sample matrices e.g. silicates won’t digest with this
acid. In such cases, HF can be used, but then inert sample introduction
systems must be used and special care must be taken while handling
this hazardous acid.  Dilute (2%) HNO  is the most preferred acid for
3
sample dilution in ICP-MS, as polyatomic ions are not increased and
nitric acid is readily available in a high purity form.
sunshinebear1
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原文由 zsdzsdzsd 发表:
老任去买一本ICP-MS手册好了,介绍的很全的。

推荐本具体的好么,手里有本王小如的ICPMS应用手册,但是有些东西还是没有。不够全。编书的都是安捷伦的技术支持,也不全面。
laidekeai
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原文由 zsdzsdzsd 发表:
老任去买一本ICP-MS手册好了,介绍的很全的。


那有卖的呀?急需啊
supercat
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For sample digestion, and dilution, HNO3 is the preferred choice, as it
produces the least new interferences in the plasma, but it is not always
ideal, since some sample matrices e.g. silicates won’t digest with this
acid. In such cases, HF can be used, but then inert sample introduction
systems must be used and special care must be taken while handling
this hazardous acid. Dilute (2%) HNO3 is the most preferred acid for

sample dilution in ICP-MS, as polyatomic ions are not increased and
nitric acid is readily available in a high purity form.
chineyao119
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原文由 yzyxq 发表:
这是因为硝酸所带入的同位素H、N、O都是原来空气中就有的,并不带入新的同位素干扰。而硫酸和盐酸等会带入S、Cl等同位素的干扰,所以说用硝酸好一些。当然,S、Cl不会对测量元素产生干扰,那用硫酸、盐酸也没有问题。

支持楼主的观点,我都是这样人为的!
dct1983
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stephen99
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